Archive: 2016 - Moldavian Journal of the Physical Sciences

22 Dec 2016

2016
V. 15
3-4
(p.193 - 207)

Stacking interactions in the crystal structures of mixed ligand square-pyramidal copper(ii) complexes with aromatic 1,10-phenanthroline or 2,2´-bipyridine ligands and acetylacetonate

CZU: 548+53

Authors:

Melnic, Elena

Summary:

Four novel mononuclear square-pyramidal complexes with composition [Cu(acac)(phen)(DMF)]BF4 (1), [Cu(acac)(phen)(H2O)]BF4 (2), [Cu(acac)(phen)(NO3)]MeOH (3) and [Cu(acac)(phen)Cl]MeOH (4), (phen = phenanthroline and acac = acetylacetonate) have been synthesized and characterized by single-crystal X-ray diffraction. The supramolecular structures of these novel complexes and related complexes found in the Cambridge Structural Database (CSD), which contain a planar [Cu(acac)(AA)] fragment, where AA denotes phen or 2,2´-bipyridine (bipy)/4,4´-dimethyl-2,2´-dipyridine (Me2bipy), have been analyzed from in terms of stacking interactions in these systems.

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BibTeX

@article{ibn_50387,
author = {Melnic, E.I.},
title = {Stacking interactions in the crystal structures of mixed ligand square-pyramidal copper(ii) complexes with aromatic 1,10-phenanthroline or 2,2´-bipyridine ligands and acetylacetonate},
journal = {Moldavian Journal of the Physical Sciences},
year = {2016},
volume = {15 (3-4)},
pages = {193-207},
month = {Dec},
abstract = {(EN) Four novel mononuclear square-pyramidal complexes with composition [Cu(acac)(phen)(DMF)]BF4 (1), [Cu(acac)(phen)(H2O)]BF4 (2), [Cu(acac)(phen)(NO3)]MeOH (3) and [Cu(acac)(phen)Cl]MeOH (4), (phen = phenanthroline and acac = acetylacetonate) have been synthesized and characterized by single-crystal X-ray diffraction. The supramolecular structures of these novel complexes and related complexes found in the Cambridge Structural Database (CSD), which contain a planar [Cu(acac)(AA)] fragment, where AA denotes phen or 2,2´-bipyridine (bipy)/4,4´-dimethyl-2,2´-dipyridine (Me2bipy), have been analyzed from in terms of stacking interactions in these systems. },
url = {https://ibn.idsi.md/vizualizare_articol/50387},
}

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<dc:description xml:lang='en'>Four novel mononuclear square-pyramidal complexes with composition [Cu(acac)(phen)(DMF)]BF4 (1), [Cu(acac)(phen)(H2O)]BF4 (2), [Cu(acac)(phen)(NO3)]MeOH (3) and [Cu(acac)(phen)Cl]MeOH (4), (phen = phenanthroline and acac = acetylacetonate) have been synthesized and characterized by single-crystal X-ray diffraction. The supramolecular structures of these novel complexes and related complexes found in the Cambridge Structural Database (CSD), which contain a planar [Cu(acac)(AA)] fragment, where AA denotes phen or 2,2´-bipyridine (bipy)/4,4´-dimethyl-2,2´-dipyridine (Me2bipy), have been analyzed from in terms of stacking interactions in these systems. </dc:description>
<dc:source>Moldavian Journal of the Physical Sciences 15 (3-4) 193-207</dc:source>
<dc:title>Stacking interactions in the crystal structures of mixed ligand square-pyramidal copper(ii) complexes with aromatic 1,10-phenanthroline or 2,2´-bipyridine ligands and acetylacetonate</dc:title>
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“ ... ”

SM ISO690:2012

MELNIC, Elena. Stacking interactions in the crystal structures of mixed ligand square-pyramidal copper(ii) complexes with aromatic 1,10-phenanthroline or 2,2´-bipyridine ligands and acetylacetonate. In: Moldavian Journal of the Physical Sciences. 2016, nr. 3-4(15), pp. 193-207. ISSN 1810-648X.