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  • Archive: 2011
05 Feb 2011
  • 2011
  • V. 10
  • 1
  • (p.26 - 32)

Magnetic circular dichroism study of the exchange-coupled Cobalt(II) dimer.

Authors:

Ostrovschii, Serghei

Summary:

MCD spectrum of the exchange coupled [Co2(μ-H2O)(μ-OAc)2(OAc)2(tmen)2] complex was analyzed. The analysis is based on the assumption that weak exchange interaction does not change the optical properties of the interacting ions and affects the saturation magnetization behavior only. The feature of MCD behavior, namely, the disappearance of some lines with increasing magnetic field and appearance again with the opposite sign, was explained by the overlap of the electronic transitions at different but near wavelengths.

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BibTeX

@article{ibn_4300,
author = {Ostrovschii, S.M.},
title = {Magnetic circular dichroism study of the exchange-coupled Cobalt(II) dimer. },
journal = {Moldavian Journal of the Physical Sciences},
year = {2011},
volume = {10 (1)},
pages = {26-32},
month = {Feb},
abstract = {(EN) MCD  spectrum  of  the  exchange  coupled  [Co2(μ-H2O)(μ-OAc)2(OAc)2(tmen)2]  complex 
was analyzed. The analysis  is based on  the assumption  that weak exchange  interaction does not 
change  the  optical  properties  of  the  interacting  ions  and  affects  the  saturation  magnetization 
behavior  only.  The  feature  of MCD  behavior,  namely,  the  disappearance  of  some  lines  with 
increasing magnetic  field  and  appearance  again with  the  opposite  sign, was  explained  by  the 
overlap of the electronic transitions at different but near wavelengths. },
url = {https://ibn.idsi.md/vizualizare_articol/4300},
}

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was analyzed. The analysis  is based on  the assumption  that weak exchange  interaction does not 
change  the  optical  properties  of  the  interacting  ions  and  affects  the  saturation  magnetization 
behavior  only.  The  feature  of MCD  behavior,  namely,  the  disappearance  of  some  lines  with 
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<dc:creator>Ostrovschii, S.M.</dc:creator>
<dc:date>2011-02-05</dc:date>
<dc:description xml:lang='en'>MCD  spectrum  of  the  exchange  coupled  [Co2(μ-H2O)(μ-OAc)2(OAc)2(tmen)2]  complex 
was analyzed. The analysis  is based on  the assumption  that weak exchange  interaction does not 
change  the  optical  properties  of  the  interacting  ions  and  affects  the  saturation  magnetization 
behavior  only.  The  feature  of MCD  behavior,  namely,  the  disappearance  of  some  lines  with 
increasing magnetic  field  and  appearance  again with  the  opposite  sign, was  explained  by  the 
overlap of the electronic transitions at different but near wavelengths. </dc:description>
<dc:source>Moldavian Journal of the Physical Sciences 10 (1) 26-32</dc:source>
<dc:title>Magnetic circular dichroism study of the exchange-coupled Cobalt(II) dimer. </dc:title>
<dc:type>info:eu-repo/semantics/article</dc:type>
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SM ISO690:2012

OSTROVSKY, Sergei M.. Magnetic circular dichroism study of the exchange-coupled Cobalt(II) dimer. . In: Moldavian Journal of the Physical Sciences. 2011, nr. 1(10), pp. 26-32. ISSN 1810-648X.

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