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  • Archive: 2009
05 May 2009
  • 2009
  • V. 8
  • 2
  • (p.207 - 213)

Structure and luminescence properties of porous alumina templates doped with rare earth elements and transition metals

Authors:

Enachi, Mihail; Trofim, Viorel; Tighineanu, Ion; Coseac, Valeriu; Ursachi, Veaceslav

Summary:

We propose to develop phosphor materials on the basis of porous alumina templates doped with rare earth elements and transition metals. This issue is especially important in connection with the development of random lasers, since the scattering properties of the porous template can de controlled by tailoring its morphology. In this work, we demonstrate that, apart from the morphology, the crystallographic structure of the template can be controlled by the conditions of post-anodization thermal treatment applied for the activation of the impurity impregnated from rare earth or transition metal containing solutions. The initially amorphous alumina structure is transformed into a γ-Al2O3 phase by annealing at 300–700°C. A δ-Al2O3 phase is predominant in samples annealed at 800–1000°C. The samples annealed at temperatures above 1100°C exhibit an α-Al2O3 structure. The technological conditions related to the solution concentration and duration of impregnation, postimpregnation annealing temperature and annealing duration were optimized from the point of view of maximum impurity ion activation.

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BibTeX

@article{ibn_4114,
author = {Enachi, M.A. and Trofim, V.G. and Tighineanu, I.M. and Coseac, V. and Ursachi, V.V.},
title = {Structure and luminescence properties of 
porous alumina templates doped with 
rare earth elements and transition metals 
},
journal = {Moldavian Journal of the Physical Sciences},
year = {2009},
volume = {8 (2)},
pages = {207-213},
month = {May},
abstract = {(EN) We propose to develop phosphor materials on the basis of porous alumina templates 

doped with rare earth elements and transition metals. This issue is especially important in connection with the development of random lasers, since the scattering properties of the porous 
template can de controlled by tailoring its morphology. In this work, we demonstrate that, apart 
from the morphology, the crystallographic structure of the template can be controlled by the 
conditions of post-anodization thermal treatment applied for the activation of the impurity impregnated from rare earth or transition metal containing solutions. The initially amorphous alumina structure is transformed into a γ-Al2O3 phase by annealing at 300–700°C. A δ-Al2O3 phase 
is predominant in samples annealed at 800–1000°C. The samples annealed at temperatures 
above 1100°C exhibit an α-Al2O3 structure. The technological conditions related to the solution 
concentration and duration of impregnation, postimpregnation annealing temperature and annealing duration were optimized from the point of view of maximum impurity ion activation. 

 },
url = {https://ibn.idsi.md/vizualizare_articol/4114},
}

DataCite

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<title xml:lang='ro'>Structure and luminescence properties of 
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<description xml:lang='en' descriptionType='Abstract'>We propose to develop phosphor materials on the basis of porous alumina templates 

doped with rare earth elements and transition metals. This issue is especially important in connection with the development of random lasers, since the scattering properties of the porous 
template can de controlled by tailoring its morphology. In this work, we demonstrate that, apart 
from the morphology, the crystallographic structure of the template can be controlled by the 
conditions of post-anodization thermal treatment applied for the activation of the impurity impregnated from rare earth or transition metal containing solutions. The initially amorphous alumina structure is transformed into a γ-Al2O3 phase by annealing at 300–700°C. A δ-Al2O3 phase 
is predominant in samples annealed at 800–1000°C. The samples annealed at temperatures 
above 1100°C exhibit an α-Al2O3 structure. The technological conditions related to the solution 
concentration and duration of impregnation, postimpregnation annealing temperature and annealing duration were optimized from the point of view of maximum impurity ion activation. 

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Dublin Core

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<dc:creator>Enachi, M.A.</dc:creator>
<dc:creator>Trofim, V.G.</dc:creator>
<dc:creator>Tighineanu, I.M.</dc:creator>
<dc:creator>Coseac, V.</dc:creator>
<dc:creator>Ursachi, V.V.</dc:creator>
<dc:date>2009-05-05</dc:date>
<dc:description xml:lang='en'>We propose to develop phosphor materials on the basis of porous alumina templates 

doped with rare earth elements and transition metals. This issue is especially important in connection with the development of random lasers, since the scattering properties of the porous 
template can de controlled by tailoring its morphology. In this work, we demonstrate that, apart 
from the morphology, the crystallographic structure of the template can be controlled by the 
conditions of post-anodization thermal treatment applied for the activation of the impurity impregnated from rare earth or transition metal containing solutions. The initially amorphous alumina structure is transformed into a γ-Al2O3 phase by annealing at 300–700°C. A δ-Al2O3 phase 
is predominant in samples annealed at 800–1000°C. The samples annealed at temperatures 
above 1100°C exhibit an α-Al2O3 structure. The technological conditions related to the solution 
concentration and duration of impregnation, postimpregnation annealing temperature and annealing duration were optimized from the point of view of maximum impurity ion activation. 

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<dc:source>Moldavian Journal of the Physical Sciences 8 (2) 207-213</dc:source>
<dc:title>Structure and luminescence properties of 
porous alumina templates doped with 
rare earth elements and transition metals 
</dc:title>
<dc:type>info:eu-repo/semantics/article</dc:type>
</oai_dc:dc>

        

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ENACHI, Mihail; TROFIM, Viorel; TIGHINEANU, Ion; COSEAC, Valeriu; URSACHI, Veaceslav. Structure and luminescence properties of porous alumina templates doped with rare earth elements and transition metals . In: Moldavian Journal of the Physical Sciences. 2009, nr. 2(8), pp. 207-213. ISSN 1810-648X.

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