Archive: 2008 - Moldavian Journal of the Physical Sciences

05 Jul 2008

2008
V. 7
3
(p.382 - 388)

Synthesis and structure of condensation product of dimethylglyoxime on gold matri

Authors:

Bouroş, Pavlina; Simonov, Iurii; Bologa, Olga; Lipkowski, Janusz

Summary:

Complex of gold of the composition [AuL(NO2)] (1), where HL is a new tridentate ligand obtained by the condensation of two dimethylglyoxime (H2DMG) molecules on the matrix of the gold ion, was synthesized and characterized by X-ray structural analysis. It was shown that in the system H[AuCl4] . 4Н2О H2DMG Py, depending on pH of the reaction medium and sequence of addition of components, the final products have unexpected compositions ([AuIII (DMG)ClPy], [AuCl2Py2][AuCl4] . 2[AuCl3Py] or [AuII L(NO2)]). Molecular complex 1 is sustained by the Au....Au…Au intermolecular nteractions.

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BibTeX

@article{ibn_3924,
author = {Bouroş, P.N. and Simonov, I.A. and Bologa, O.A. and Lipkowski, J.},
title = {Synthesis and structure of condensation product of dimethylglyoxime on gold matri },
journal = {Moldavian Journal of the Physical Sciences},
year = {2008},
volume = {7 (3)},
pages = {382-388},
month = {Jul},
abstract = {(EN) Complex of gold of the composition [AuL(NO2)] (1), where HL is a new tridentate 

ligand obtained by the condensation of two dimethylglyoxime (H2DMG) molecules on the 
matrix of the gold ion, was synthesized and characterized by X-ray structural analysis. It was 
shown that in the system H[AuCl4]
. 4Н2О   H2DMG   Py, depending on pH of the reaction 
medium and sequence of addition of components, the final products have unexpected compositions ([AuIII
(DMG)ClPy], [AuCl2Py2][AuCl4]
.
2[AuCl3Py] or [AuII
L(NO2)]). Molecular 
complex 1 is sustained by the Au....Au…Au intermolecular nteractions. },
url = {https://ibn.idsi.md/vizualizare_articol/3924},
}

DataCite

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ligand obtained by the condensation of two dimethylglyoxime (H2DMG) molecules on the 
matrix of the gold ion, was synthesized and characterized by X-ray structural analysis. It was 
shown that in the system H[AuCl4]
. 4Н2О   H2DMG   Py, depending on pH of the reaction 
medium and sequence of addition of components, the final products have unexpected compositions ([AuIII
(DMG)ClPy], [AuCl2Py2][AuCl4]
.
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Dublin Core

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<dc:description xml:lang='en'>Complex of gold of the composition [AuL(NO2)] (1), where HL is a new tridentate 

ligand obtained by the condensation of two dimethylglyoxime (H2DMG) molecules on the 
matrix of the gold ion, was synthesized and characterized by X-ray structural analysis. It was 
shown that in the system H[AuCl4]
. 4Н2О   H2DMG   Py, depending on pH of the reaction 
medium and sequence of addition of components, the final products have unexpected compositions ([AuIII
(DMG)ClPy], [AuCl2Py2][AuCl4]
.
2[AuCl3Py] or [AuII
L(NO2)]). Molecular 
complex 1 is sustained by the Au....Au…Au intermolecular nteractions. </dc:description>
<dc:source>Moldavian Journal of the Physical Sciences 7 (3) 382-388</dc:source>
<dc:title>Synthesis and structure of condensation product of dimethylglyoxime on gold matri </dc:title>
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“ ... ”

SM ISO690:2012

BOUROSH, Pavlina; SIMONOV, Yurii A.; BOLOGA, Olga; LIPKOWSKI, Janusz. Synthesis and structure of condensation product of dimethylglyoxime on gold matri . In: Moldavian Journal of the Physical Sciences. 2008, nr. 3(7), pp. 382-388. ISSN 1810-648X.